Publications

Published Manuscripts:

2024

 

Timokhin, V.; Grigg, R.; Schomaker, J. M. Mechanistic Insights into Ru-Catalyzed Alkene Epoxidation with Nitrous Oxide as a Terminal Oxidant. Eur. J. Inorg. Chem. 2024.

Nicastri, K. A.; Gerstner, N. C.; Schomaker, J. M. Progress toward the Total Synthesis of Jogyamycin Using a Tandem Ichikawa/Winstein Rearrangement. Org. Lett. 2023, 25 (46), 8279–8283.

 

Ward, R. M.; Hu, Y.; Tu, N.; Schomaker, J. M. Solvent effects on the chemo- and site-selectivity of transition metal-catalyzed heterogeneous nitrene transfer reactions: Alternatives to chlorinated solvents. ChemSusChem 2023.

Lee, K.; Seo, K.; Dehghany, M.; Hu, Y.; Trinh, A.; Schomaker, J. M. An Overview of N-Heterocycle Syntheses Involving Nitrene Transfer Reactions. In Heterocycles from Carbenes and Nitrenes: Methods, Reactions and Synthetic Applications, 2023, 313–377.

Dequina, H. J.; Jones, C. L.; Schomaker, J. M. Recent updates and future perspectives in aziridine synthesis and reactivity. Chem 2023, 9 (7), 1658–1701.

Trinh, T. A.; Schomaker, J. M. Unnatural α-amino acid synthesis. Nat. Synth. 2023, 2 (7), 600–601.

Chanda, B.; Ursulaez, W. C.; Schomaker, J. M.; Jones, C. L.; Dehghany, M. Compounds and methods for forming ion channels in biological membranes. US Patent App. 17/881,038, Pub. No. US 2023/0060873 A1, March 2, 2023.

2022

Choi, I. Trenerry, M. Lee, K. King, N.; Berry, J. F.; Schomaker, J. M. Divergent C-H aminations and iminations by tuning electrochemical reaction potentials. ChemSusChem. 2022

Fu, Y. Zerull, E. E. Schomaker, J. M. Liu, P. Origins of catalyst-controlled selectivity in the Ag-catalyzed regiodivergent C-H amination. J. Am. Chem. Soc. 2022, 144, 2735-2746.

Liu, W. Choi, I. Zerull, E. E. Schomaker, J. M. Tunable silver-catalyzed nitrene transfer: From chemoselectivity to enantioselective C-H amination. ACS Catal. 2022, 12, 5527-5539.

Vine, L. E. Schomaker, J. M. Back to basics. Nat. Chem. 2022,

Zerull, E. E. Schomaker, J. M. Chiral amine synthesis refashioned. Nat. Synthesis 2022, 1, 506-507.

Ward, R. M. Schomaker, J. M. C-H amination via hydrogen atom transfer. in Handbook of CH-Functionalization (CHF) John Wiley & Sons: Chichester, UK, 2022, 13, 1-37.

Zerull, E. E. Kim, J. Trinh, A. Schomaker, J. M. C-H functionalization via asymmetric nitrene transfer in Handbook of CH-Functionalization (CHF) John Wiley & Sons: Chichester, UK, 2022, in press.

Carrasquel-Ursulaez, W. Dehghany, M. Jones, C. L. Idikuda, V. Lu, B. Schomaker, J. M. Chanda, B. Synthetic ion channels: functional characterization of benzo-crown ether based derivatives, Biophys. 2022, 121, 248a.

Carrasquel-Ursulaez, W. Dehghany, M. Jones, C. L. Idikuda, V. Lu, B. Schomaker, J. M. Chanda, B. Acylated and alkylated benzo(crown-ethers) form ion-dependent ion channels in biological membranes, Biophys. 2022, 121, 1105-1114.

Fu, Y. Zerull, E. E. Schomaker, J. M.* Liu, P. Origins of Catalyst-Controlled Selectivity in Ag-Catalyzed Regiodivergent C–H Amination, J. Am. Chem. Soc. 2022.

 

Nicastri, K.A. Zappia, S. A. Pratt, J. C. Duncan, J. M. Guzei, I. A. Fernández*, I. Schomaker*, J. M. Tunable Aziridinium Ylide Reactivity: Noncovalent Interactions Enable Divergent Product Outcomes, ACS Catal. 2022, 12, 1572–1580. 

2021

Vine, L.E. Schomaker. J. M. Pd-Catalyzed Heck-Type Reactions of Allenes for Stereoselective Syntheses of Substituted 1,3-Dienes, Eur. J. Org. Chem. 2021.

Dequina, H. J. Nicastri, K. A. Schomaker. J. M. Additions of N, O, and S heteroatoms to metal-supported carbenes: Mechanism and synthetic applications in modern organic chemistry, Adv.Organomet.Chem. 2021, 76, 1-100.

Vine, E. L. Reeves, R. D. Landwehr, E. M. Fernandez, I.; Schomaker, J. M Scope and Mechanistic Investigations of Pd-Catalyzed Coupling/Cyclization and Cycloisomerization of Allenyl Malonate, ACS Catal. 2021, 11, 9485–9494.

Hu, Y. Schomaker, J. M Recent developments and strategies for mutually orthogonal bioorthogonal reactions, ChemBioChem, 2021.

Ward, R. M. Schomaker, J. M. Allene Trifunctionalization via Amidyl Radical Cyclization and TEMPO Trapping, J. Org. Chem. 2021, 86, 13, 8891-8899.

Ju, M. Schomaker, J. M. Modern Catalyst Design Strategies for Enantioselective Formation of C-N Bonds via Nitrene Transfer. Nat. Rev. Chem. 2021.

Dehghany, M.; Schomaker, J. M. Silver-catalyzed Enantioselective Functionalizations of Alkenes and Alkynes: A Short Review, Curr. Opin. Green Sustain. Chem., 2021, 30, 100483.

2020

Carrasquel Ursulaez, W.; Reeves, R. D.; Dehghany, M.; Jones, C.; Schomaker, J. M.; Chanda, B. Re-evaluation of the mechanism of cytotoxicity dialkylated lariat ether compounds. RSC Adv. 2020, 10, 40391-40394.

Hu, Y.; Robert, J. M.; Kilgore, H.; Mat Lani, A. S.; Raines, R. T.; Schomaker, J. M. Triple, Mutually Orthogonal Cycloadditions Through the Design of Electronically Activated SNO-OCTs. J. Am. Chem. Soc. 2020. 142, 44, 18826–18835.

Nicastri, K. A.; Schomaker, J. M. DMDO. Encyclopedia of Reagents for Organic Synthesis, 2020, accepted, in press.

Vine, L. E.; Zerull, E. E.; Schomaker, J. M. Taming nitrene transfer with silver catalysts. Synlett, 2020.

U.S. Patent: Electronically Activated Strained Alkynes. Inventors. Schomaker, J. M.; Burke, E. G. US10676449B2, issued June 2020.

Ju, M.; Zerull, E. E.; Roberts, J. M.; Huang, M.; Schomaker, J. M. Silver-Catalyzed Enantioselective Propargylic C–H Bond Amination Through Rational Ligand Design. J. Am. Chem. Soc. 2020. 142, 30, 12930–12936

Lu, L.; Ward, R. M.; Schomaker, J. M. Regioselective intramolecular allene amidation enabled by an EDA complex. Eur. J. Org. Chem. 2020. 26, 13783 –13787

Gerstner, N. C.; Nicastri, K. A.; Schomaker, J. M. Strategies for the synthesis of pactamycin and jogyamycin. Angew. Chem. Int. Ed. 2021. 60, 2–22

Huang, M.; Paretsky, J.; Schomaker, J. M. Rigidifying Ag(I) Complexes for Selective Nitrene Transfer. ChemCatChem. 2020, 12, 3076-3081.

Nicastri, K.; Schomaker, J. M. 1, 2-Azide Migration Enables Synthesis of β-Difluoroalkyl Azides. Chem. 2020, 6, 327-329.

Schomaker, J. M. Interview with Jennifer M. Schomaker. Org. Chem. Front., 2020, 7, 442-444.

Eshon, J. Ring expansion of aziridines to dehydropiperidines. Nature Research Chemistry Community.

Eshon, J.; Nicastri, K.; Schmid, S. C.; Raskop, W.; Guzei, I. A.; Fernández, I.; Schomaker, J. M. Intermolecular [3+3] Ring-Expansion of Aziridines to Dehydropiperidines through the Intermediacy of Aziridinium Ylides. Nat. Commun., 2020, 12, 1273.

Corbin, J. R.; Ketelboeter, D. R.; Fernández, I.; Schomaker, J. M. Biomimetic Imino-Nazarov Cyclizations via Eneallene Aziridination. J. Am. Chem. Soc. 2020, 142, 12, 5568-5573.

Reeves, R. D.; Kinkema, C. N.; Landwehr, E. M.; Vine, L. E.; Schomaker, J. M. Stereodivergent Metal-catalyzed Allene Cycloisomerizations. Synlett., 2020, 31, 627-631.

2019

Liu, L.; Ward, R. M.; Schomaker, J. M. Mechanistic Aspects and Synthetic Applications of Radical Additions to Allenes. Chem. Rev. 2019, 119, 12422-12490.

Ju, M.; Guan, W.; Schomaker, J. M.; Harper, K. C. Sequential Reduction of Nitroalkanes Mediated by CS₂ and Amidine/Guanidine Bases: a Controllable Nef Reaction. Org. Lett. 2019, 21, 8893-8898.

Gerstner, N. C.; Schomaker, J. M. Stereocontrolled Synthesis of the Aminocyclopentitol Core of Jogyamycin via an Ichikawa Rearrengment Reaction. ChemRxiv preprint, 2019, 84, 14092-14100.

Scamp, R. J.; Sheffer, B.; Schomaker, J. M. Regioselective differentiation of vicinal methylene C-H bonds enabled by silver-catalyzed nitrene transfer. Chem. Commun. 2019, 55, 7362-7365.

Ju, M.; Huang, M.; Vine, L.; Dehghany, M.; Roberts, J. M.; Schomaker, J. M. Tunable, Catalyst-Controlled Syntheses Of Beta- And Gamma-Amino Alcohol Motifs Enabled By Silver Complexes. Nature Catalysis 2019, 2, 899-908.

Dehghany, M.; Eshon, J.; Roberts, J. M.; Schomaker, J. M. Silver-Catalyzed Carbene, Nitrene And Silylene Transfer Reactions. in Silver in Organic Synthesis Wiley-VCH Verlag GmbH & Co.: Weinheim, 2019, 439-532.

2018

Eshon, J.; Foarta, F.; Landis, C. R.; Schomaker, J. M. Alpha-Tetrasubstituted Aldehydes Through Electronic And Strain-Controlled Branch-Selective Stereoselective Hydroformylation. J. Org. Chem. 2018, 83, 10207-10220.

Eshon, J.; Gerstner, N. C.; Schomaker, J. M. Oxidative Allene Amination For The Synthesis Of Nitrogen-Containing Heterocycles. Arkivoc 2018, 204-233.

Mat Lani, A. S.; Schomaker, J. M. Site-Selective, Catalyst-Controlled Alkene Aziridination. Synthesis issue in honor of Professor Scott Denmark’s 65th birthday, 2018, 50, 4462-4470.

Schomaker, J. M.; Burke, E. G. Electronically Activated Strained Alkynes. From U.S. Pat. Appl. Publ. (2018), US 20180201593 A1 20180719.

Schmid, S. C.; Guzei, I. A.; Fernandez, I.; Schomaker, J. M. Ring Expansion Of Bicyclic Methyleneaziridines Via Concerted, Near-Barrierless [2,3]-Stevens Rearrangements Of Aziridinium Ylides. ACS Catal. 2018, 8, 7907-7914.

Tansukawat, N. D.; See, A. E.; Jiranuntarat, S.; Corbin, J. R.; Schomaker, J. M. Method For The Small-Scale Production Of Deuterochloroform. J. Org. Chem. 2018, 83, 8739-8742.

Alderson, J. M.;  Corbin, J. R.; Schomaker, J. M. Investigation Of Transition Metal-Catalyzed Nitrene Transfer Reactions In Water. Bioorg. Med. Chem. issue in honor of Professor Laura Kiessling’s Tetrahedron Prize, 2018, 26, 5270-5273.

Liu, L.; Schomaker, J. M.  Allene Aziridination As A Tool For The Synthesis Of Complex Amines. in Advances in Transition-Metal Mediated Heterocycle Synthesis, Fernandez, I. Ed.; Elsevier, 2018, pp 231-283.

2017

Huang, M.; Yang, T.; Paretsky, J. D.; Berry, J. F.; Schomaker, J. M. Inverting Steric Effects: Using ‘Attractive’ Non-Covalent Interactions To Direct Silver-Catalyzed Nitrene Transfer. J. Am. Chem. Soc. 2017, 139, 17376-17386.

Vinokur, A. I.; Yakovenko, A.; Liu, L.; Schomaker, J. M.; Guzei, I. A. An Enantiotropic Disorder-Partial Order Solid-State Transformation In A Molecular Solid Involving A Phase With Z’=12. Cryst. Growth Des. 2017, 17, 5984-5993.

Schmid, S. C.; Guzei, I. A.; Schomaker, J. M.  A Stereoselective [3+1] Ring Expansion Of The Synthesis Of Highly Substituted Methylene Azetidines. Angew. Chem. Int. Ed. 2017, 56, 12229-12233.

Burke, E. G.; Schomaker, J. M. Synthetic Applications Of Flexible SNO-OCT Strained Alkynes and Their Use in Postpolymerization Modifications. J. Org. Chem. 2017, 82, 9038-9046.

Alderson, J. M.; Corbin, J. R.; Schomaker, J. M. Tunable, Chemo- And Site-Selective Nitrene Transfer Reactions through the Rational Design of Silver(I) Catalysts. Acc. Chem. Res.2017, 50, 2147-2158.

Ju, M.; Weatherly, C. D.; Guzei, I. A.; Schomaker, J. M. Chemo- and Enantioselective Intramolecular Silver-Catalyzed Aziridinations. Angew. Chem. Int. Ed. 2017, 56, 9944-9948.

Eshon, J.; Landis, C. R.; Schomaker, J. M. Regioselective Rh-Catalyzed Hydroformylation of 1,1,3-Trisubstituted Allenes Using BisDiazaPhos Ligand. J. Org. Chem. 2017, 9270-9278.

Alderson, J. M.; Schomaker, J. M. Tandem Oxidative Derivatization of Nitrene Insertion Products for the Highly Diastereoselective Synthesis of 1,3-aminoalcohols. Chem. Eur. J.2017, 23, 8571-8576.

Reeves, R. D.; Phelps, A. M.; Raimbach, W. A. T.; Schomaker, J. M. Diastereoselective Au-Catalyzed Allene Cycloisomerizations to Highly Substituted Cyclopentenes. Org. Lett. 2017, 19, 3394-3397.

Liu, L.; Gerstner, N. C.; Oxtoby, L. J.; Guzei, I. A.; Schomaker, J. M. Fluorinated Amine Stereotriads via Allene Amination. Org. Lett. 2017, 19, 3239-3242.

Burke, E. G.; Gold, B.; Hoang, T. T.; Raines, R. T.; Schomaker, J. M. Fine-Tuning Strain and Electronic Activation of Strain-Promoted 1,3-Dipolar Cycloadditions with Endocyclic Sulfamates in SNO-OCTs. J. Am. Chem. Soc. 2017, 139, 8029-8037.

Huang, M.; Corbin, J. R.; Dolan, N. S.; Fry, C. G.; Vinokur, A.; Guzei, I. A.; Schomaker, J. M. Synthesis, Characterization, And Variable-Temperature Nmr Studies Of Silver(I) Complexes For Selective Nitrene Transfer. Inorg. Chem. 2017, No. 56, 6725-6733.

Weatherly, C. D.; Alderson, J. M.; Berry, J. F.; Hein, J.; Schomaker, J. M. Catalyst-Controlled Nitrene Transfer by Tuning Metal:Ligand Ratios: Insight into the Mechanisms of Chemoselectivity. Organometallics 2017, 36, 1649-1661.

Corbin, J. R.; Schomaker, J. M. Tunable Differentiation of Tertiary C-H Bonds in Intramolecular Transition Metal-Catalyzed Nitrene Transfer Reactions. Chem. Commun. 2017, 53, 4346-4349.

2016

Dolan, N. S.; Scamp, R. J.; Yang, T.; Berry, J. F.; Schomaker, J. M. Catalyst-Controlled And Tunable, Chemoselective Silver-Catalyzed Intermolecular Nitrene Transfer: Experimental And Computational Studies. J. Am. Chem. Soc. 2016, 138, 14658-14667.

Touney, E. E.; Van Hoveln, R.; Buttke, C. T.; Freidberg, M. D.; Guzei, I. A.; Schomaker, J. M. Heteroleptic Nickel Complexes for the Markovnikov-Selective Hydroboration of Styrenes. Organometallics 2016, 35, 3436.

Phelps, A. M.; Chan, V. S.; Napolitano, J. G.; Krabbe, S. W.; Schomaker, J. M.; Shekhar, S. Ligand-Controlled Synthesis of Azoles via Ir-Catalyzed Reactions Of Sulfoxonium Ylides With 2-Amino Heterocycles. J. Org. Chem. 2016, 81, 4158.

Gerstner, N.; Adams, C. S.; Schomaker, J. M. Stereocontrolled Syntheses of Seven-Membered Carbocycles by Tandem Allene Aziridination/[4+3] Reaction. Angew. Chem. Int. Ed.2016, 55, 13240.

Scamp, R. J.; Jirak, J. G.; Dolan, N. S.; Guzei, I. A.; Schomaker, J. M. A General Catalyst for Site-Selective C(Sp³)-H Bond Amination of Activated Secondary over Tertiary Alkyl C(Sp³)-H Bonds. Org. Lett. 2016, 18, 3014-3017.

Gerstner, N. C.; Adams, C. S.; Grigg, R. D.; Tretbar, M.; Rigoli, J. W.; Schomaker, J. M. Diastereoselective Synthesis of the Aminocyclitol Core of Jogyamycin via an Allene Aziridination Strategy. Org. Lett. 2016, 18, 284.

2015

Phelps, A. M.; Alderson, J. M.; Schomaker, J. M.; Ma, S.; Gao, S. Metal-Catalyzed Cyclization Reactions Of Allenes. Chapter 6 In Science of Synthesis; 2015.

Burke, E. G.; Schomaker, J. M. Oxidative Allene Amination for the Synthesis of Azetidin-3-ones. Angew. Chem. Int. Ed. 2015, 54, 12097.

Schmid, S. C.; Van Hoveln, R. J.; Rigoli, J. W.; Schomaker, J. M. Development of N-Heterocyclic Carbene-Copper Complexes for 1,3-Halogen Migration. Organometallics 2015, 34, 4164.

Croisant, M. F.; Van Hoveln, R. J.; Schomaker, J. M. Formal Dyotropic Rearrangements In Organometallic Transformations. Eur. J. Org. Chem. 2015. 

Van Hoveln, R. J.; Hudson, B. M.; Wedler, H. B.; Bates, D. M.; Le Gros, G.; Tantillo, D. J.; Schomaker, J. M. Mechanistic Studies of Copper(I)-Catalyzed 1,3-Halogen Migration. J. Am. Chem. Soc. 2015, 137, 5346.

2014

Alderson, J. M.; Phelps, A. M.; Scamp, R. J.; Dolan, N. S.; Schomaker, J. M. Ligand-Controlled, Tunable Silver-Catalyzed C-H Amination. J. Am. Chem. Soc. 2014, 136.

Van Hoveln, R.; Schmid, S.; Schomaker, J. M. 1,3-Halogen Migration as an Entry to Aryl Coppers from an Unintuitive Starting Material. Org. Biomol. Chem. 2014, 12.

Van Hoveln, R. J.; Schmid, S. C.; Tretbar, M.; Buttke, C.; Schomaker, J. M. Formal Asymmetric Hydrobromination of Styrenes via Copper-Catalyzed 1,3-Halogen Migration. Chem. Sci. 2014, 5, 4763.

 Adams, C. S.; Grigg, R. D.; Schomaker, J. M. Complete Stereodivergence in the Synthesis of 2-Amino-1,3-diols from Allenes. Chem. Sci. 2014, 5, 3046.

Adams, C. S.; Grigg, R. D.; Schomaker, J. M. Aminosugar Motifs via an Allene Aziridination Strategy. Tetrahedron 2014, 70, 4128.

Adams, C. S.; Weatherly, C. D.; Burke, E. G.; Schomaker, J. M. The Conversion of Allenes to Strained Three-Membered Heterocycles. Chem. Soc. Rev. 2014, 43, 3136.

Rigoli, J. W.; Guzei, I. A.; Schomaker, J. M. Aminodiols via Stereocontrolled Oxidation of Methyleneaziridines. Org. Lett. 2014, 16, 1696.

Scamp, R. J.; Rigoli, J. W.; Schomaker, J. M. Chemoselective Silver-Catalyzed Nitrene Insertion Reactions. Pure Appl. Chem. 2014, 86, 381.

2013

Rigoli, J. W.; Weatherly, C. D.; Alderson, J.; Vo, B. T.; Schomaker, J. M. Tunable, Chemoselective Amination via Silver Catalysis. J. Am. Chem. Soc. 2013, 135, 17238.

Weatherly, C. D.; Guzei, I. A.; Schomaker, J. M. Stereocontrolled Synthesis of 1,3-Diamino-2-ols by Aminohydroxylation of Bicyclic Methylene-Aziridines. Eur. J. Org. Chem. 2013, 2013(18), 3667-3670.

Phelps, A. M.; Dolan, N. S.; Connell, N. T.; Schomaker, J. M. Divergent Reactivity of Allene-Containing Alpha-Diazoesters using Cu and Rh Catalysts. Tetrahedron 2013, 69, 5614-5621.

Grigg, R. D.; Schomaker, J. M. Activating Group Recycling: A Fresh Approach to Arene Functionalization. Synlett 2013, 24, 401.

Rigoli, J. W.; Weatherly, C. D.; Vo, B. T.; Neale, S.; Meis, A. R.; Schomaker, J. M. Chemoselective Allene Aziridination via Ag(I) Catalysis. Org. Lett. 2013, 15, 290.

Schomaker, J. M.; Boralsky, L. A.; Rigoli, J. W.; Hershberger, J. C. Efficient Processes to Prepare Asymmetric, Hetereoatom-Bearing Stereotriads via Allene Oxidation. 2013-US-79511, 2013.

2012

Grigg, R. D.; Van Hoveln, R.; Schomaker, J. M. Copper-Catalyzed Recycling of Halogen Activating Groups via 1,3-Halogen Migration. J. Am. Chem. Soc. 2012, 134, 16131-16134.

Adams, C. S.; Boralsky, L. A.; Guzei, I. A.; Schomaker, J. M. Modular Functionalization of Allenes to Aminated Stereotriads. J. Am. Chem. Soc. 2012, 134, 10807-10810.

Grigg, R. D.; Rigoli, J. W.; Van Hoveln, R.; Neale, S.; Schomaker, J. M. Beyond Benzyl Grignards: Facile Generation of Benzyl Carbanions from Styrenes. Chem. Eur. J. 2012, 18, 9391-9396.

Weatherly, C. D.; Rigoli, J. W.; Schomaker, J. M. Synthesis of 1,3-Diaminated Stereotriads via Rearrangement of 1,4-Diazaspiro[2.2]pentanes. Org. Lett. 2012, 14, 1704.

Rigoli, J. W.; Boralsky, L. A.; Hershberger, J. C.; Meis, A. R.; Guzei, I. A.; Schomaker, J. M. 1,4-Diazaspiro[2.2]pentanes as a Flexible Platform for the Synthesis of Diamine-Bearing Stereotriads. J. Org. Chem. 2012, 77, 2446.

Rigoli, J. W.; Grigg, R. D.; Pearce, S. D.; Schomaker, J. M. Synthesis of Propargylic and Allenic Carbamates via the C-H Amination of Alkynes. Org. Lett. 2012, 14, 280.

Gladysz, J.; Ball, Z.; Bertrand, G.; Blum, S. A.; Dong, V. M.; Dorta, R.; Hahn, F. E.; Humphrey, M. G.; Jones, W. D.; Klosin, J.; Manners, I.; Marks, T. J.; Mayer, J. M.; Rieger, B.; Ritter, J. C.; Sattelberger, A. P.; Schomaker, J. M.; Yam, V. W. Organometallics Roundtable 2011. Organometallics 2012, 31, 1.

Rigoli, J. W.; Moyer, S. A.; Pearce, S. D.; Schomaker, J. M. alpha,beta-unsaturated Imines via Ru-Catalyzed Coupling Of Allylic Alcohols And Amines. Org. Biomol. Chem. 2012, 10.

2011

Kulshrestha, A.; Schomaker, J. M.; Holmes, D.; Staples, R. J.; Jackson, J. E.; Borhan, B. Selectivity In The Addition Reactions of Organometallic Reagents To Aziridine-2-carboxyaldehydes: The Effects Of Protecting Groups And Substitution Patterns. Chem. Eur. J. 2011, 17, 12326.

Grigg, R. D.; Schomaker, J. M.; Timokhin, V. C-H Amination/cyclocarbonylation of Allene Carbamates: A Versatile Platform for the Synthesis of alpha,beta-Unsaturated gamma-Lactams. Tetrahedron 2011, 67 (24), 4318-4326.

Boralsky, L. A.; Marston, D.; Grigg, R. D.; Hershberger, J. C.; Schomaker, J. M. Allene Functionalization via Bicyclic Methylene Aziridines. Org. Lett. 2011, 13, 1924.

Guzei, I. A.; Gunn, E. M.; Spencer, L. C.; Schomaker, J. M.; Rigoli, J. W. Polymorphism Of 5-(pyridin-2-ylmethylene)-3-phenyl-2-methylthio-3,5-dihydro-4H-imidazole-4-one. Cryst. Eng. Comm. 2011, 13, 3444-3450.

2010

Boyd, W. C.; Crimmin, M.; Rosebrugh, L.; Schomaker, J. M.; Bergman, R. G.; Toste, F. D. Cobalt-Mediated, Enantioselective Synthesis Of C₂ And C₁ Dienes. J. Am. Chem. Soc. 2010, 132, 16365.

Publications prior to UW-Madison:

Schomaker, J. M.; Toste, F. D.; Bergman, R. G. Cobalt-Mediated [3+2]-Annulation Reaction of Alkenes with alpha,beta-Unsaturated Ketones, and Imines. Org. Lett. 2009, 11 (16), 3698-3700.

Borhan, B.; Schomaker, J. M.; Bhattacharjee, S.; Korthals, K. A. Synthesis of N-Heterocycles, Beta-Amino Acids, and Allyl Amines via Aza-Payne Mediated Reaction of Ylides and Hydroxy Aziridines. U.S. Pat. Appl. Publ. 2009.

Schomaker, J. M.; Borhan, B. Total Synthesis of Haterumalides NA And NC via a Chromium-Mediated Macrocyclization. J. Am. Chem. Soc. 2008, 130, 12228-12229.

Schomaker, J. M.; Boyd, W. C.; Stewart, I. C.; Toste, F. D.; Bergman, R. G. Cobalt Dinitrosoalkane Complexes in the C-H Functionalization of Olefins. J. Am. Chem. Soc. 2008, 130, 3777-3779.

Schomaker, J. M.; Geiser, A. R.; Huang, R.; Borhan, B. Tetrasubstituted Pyrrolidines via a Tandem Aza-Payne/Hydroamination Reaction. J. Am. Chem. Soc. 2007, 129, 3794-3795.

Schomaker, J. M.; Bhattacharjee, S.; Yan, J.; Borhan, B. Diastereomerically and Enantiomerically Pure 2,3-Disubstituted Pyrrolidines from 2,3-Aziridin-1-ols using a Sulfoxonium Ylide: A One-Carbon Homologative Relay Ring Expansion. J. Am. Chem. Soc. 2007, 129, 1996-2003.

Delia, T. J.; Schomaker, J. M.; Kalinda, A. The Synthesis of Substituted Phenylpyrimidines via Suzuki Coupling Reactions. J. Heterocyclic Chem. 2006, 43, 127-131.

Zheng, T.; Narayan, R. S.; Schomaker, J. M.; Borhan, B. One-Pot Regio- and Stereoselective Cyclization of 1,2,n-triols. J. Am. Chem. Soc. 2005, 127, 6946-6947.

Schomaker, J. M.; Pulgam, V. R.; Borhan, B. Synthesis of Diastereomerically and Enantiomerically Pure 2,3-Disubstituted Tetrahydrofurans using a Sulfoxonium Ylide. J. Am. Chem. Soc.2004, 125, 13600-13601.

Schomaker, J. M.; Borhan, B. Total Synthesis Of (+)-tanikolide via Oxidative Lactonization. Org. and Biomol. Chem. 2004, 2, 621-624.

Borhan, B.; Travis, B. R.; Schomaker, J. M. Catalytic Osmium-Assisted Oxidative Cleavage of Olefins using Peroxymonosulfuric Acid and Salts Thereof. U.S. Pat. Appl. Publ. 2003.

Schomaker, J. M.; Travis, B. R.; Borhan, B. Direct Lactonization of Alkenols Via Osmium Tetroxide-Mediated Oxidative Cleavage. Org. Lett. 2003, 5, 3089-3092.

Schomaker, J. M.; Delia, T. J. Arylation Of Halogenated Pyrimidines via a Suzuki Coupling Reaction. J. Org. Chem. 2001, 66, 7125-7128.

Siddall, T. L.; Krumel, K. L.; Emonds, M. V. M.; Schomaker, J. M.; Zettler, M. W. Process for Preparing 1-alkyl-4-(2-chloro-3-alkoxy-4-alkylsulfonylbenzoyl)-5-hydroxypyrazole and Related Compounds, 2001.

Schomaker, J. M.; Delia, T. J. 2,4,6-Trichloropyrimidine. Reaction with anilines. J. Heterocyclic Chem. 2000, 37, 1457-1462.

Delia, T. J.; Meltsner, B. R.; Schomaker, J. M. 2,4,6-Trichloropyrimidine. Reaction with sodium amide. J. Heterocyclic Chem. 1999, 36, 1259-12610.

Siddall, T. L.; Edmonds, M. V. M.; Krumel, K. L.; Schomaker, J. M. Process for Preparing 1-alkyl-4-(2-chloro-3-alkoxy-4-alkylsulfonylbenzoyl)-5-hydroxypyrazole and Related Compounds, 1998.

Schomaker, J. M. Inside the Career of a Chemical Technician. American Careers 1998, 6-7.