Publications

Published Manuscripts:

2026

Trinh, T. A.; Hu, D. B.; Kenny, A. J.; Warrington, E. M.; Cherempei, S.; Guzei, I. A.; Schomaker, J. M. Chiral S(VI) Platform Unifies Selective C–H Amination of Complex Molecules and Alkane Feedstocks. Science 2026, 392, 421-428.

**Quick Read – C&EN Interview featuring Anh and Derek: Simple C–N Bond Formation with Repurposed Reagent **

Panja, S.; Trinh, T. A.; Warrington, E. M.; Hu, D. B.; Garman, L. C.; Guzei, I. A.; Schomaker, J. M. Silver-catalysed Intermolecular Benzylic-selective C–H Amidation via Nitrene Transfer. Chem. Sci. 2026 (Advance Article)

Lee, K.; Barbieri, F.; Crawford, C.; Hofstetter, H.; Schomaker, J. M. Operando NMR Monitoring of Electrochemical Reactions. Org. Process Res. Dev. 2026 (ASAP Articles)

2025

Sussman, M.; Minkoff, B.; Wolfer, J.; Hu, Y.; Schomaker, J. M. Gentle and Direct Copper-Based Protein Azidylation for Bioconjugation. US2025/0353876A1, 2025.

Lee, K.; Crawford, C.; Cheng, G.; Zerban, J.; Casali, E.; Panja, S.; Rampon, D.; Schomaker, J. Tetramethylpiperidine N-Oxyl (TEMPO)-Mediated Oxidative Functionalization of Alkoxyallenes. ChemRxiv. 2025.

Bartolomeu Halicki, P. C.; Kim, J. H.; Griffin, A. F.; Rampon, D. S.; Becker, K. L.; Seeliger, J. C.; Schomaker, J. M.; Rohde, K. H. Targeting Mycolic Acid Biosynthesis with Cyclic Sulfamates: A New Strategy against Mycobacterium Tuberculosis. ACS Infect. Dis. 2025, 11, 3071-3084.

Shiri, F.; Schomaker, J. M.; Lin, Z. Factors Influencing the Product Selectivity of Rh₂(OAc)₄ -Catalyzed Reactions of Diazoketones with Aziridines. J. Org. Chem. 2025, 90, 6549–6558.

Rampon, D. S.; Trinh, T. A.; Pan, Y.; Thein, S.; Kailing, J. W.; Guzei, I. A.; Fernández, I.; Schomaker, J. M. Two-Carbon Ring Expansion of Bicyclic Aziridines to Oxazocines via Aryne Insertion into a σ C–N Bond. Chem. Sci. 2025, 16, 20368-20375.

Kim, J. H.; Warrington, E. M.; Lee, K. S.; Hu, D. B.; Berry, J. F.; Schomaker, J. M. Solvent‐Driven Mechanistic Insights into Cu‐Catalyzed Asymmetric C─H Amidation via Nitrene Transfer. ChemCatChem. 2025, 17, e202402077

Dai, Z. Y.; Lin, C.; Hu, D. B.; Schomaker, J. M. Iron-Catalyzed Three-Component 1,2-Azidoalkylation of Conjugated Dienes via Activation of Aliphatic C‒H Bonds. Chem. Sci. 2025, 16, 6336-6344.

Seo, K.; Zhang, Y.; Trinh, T. A.; Kim, J.; Qi, L.; Guzei, I. A.; Clark, J. R.; Liu, P.; Schomaker, J. M. Mechanistic and Computational Insights into Asymmetric Intramolecular Iron-Catalyzed Nitrene Transfer into Benzylic C−H Bonds. ACS Catal. 2025, 15, 3789-3798.

Trinh, T.A.; Cherempei, S.; Rampon, D.S.; Schomaker, J.M. Site- and Stereoselective Silver-catalyzed Intramolecular Amination of Electron-deficient Heterobenzylic C–H bonds. Chem. Sci. 2025, 16, 4796-4805.

Kong, W. Y.; Hu T.; Guo W.; Potluri, A.; Schomaker, J. M.; Tantillo, D. J. Synthetically Relevant Post-Transition State Bifurcation Leading to Diradical and Zwitterionic Intermediates: Controlling Nonstatistical Kinetic Selectivity through Solvent Effects. J. Am. Chem. Soc. 2025, 147, 5310-5319.

Marris, E. T.; Rampon, D. S.; Schomaker, J. M. Reactivity of Anomalous Aziridines for Versatile Access to High Fsp3 Amine Chemical Space. Acc. Chem. Res. 2025, 58, 231–249.

Timokhin, V.; Grigg, R.; Schomaker, J. M. Mechanistic Insights into Ru-Catalyzed Alkene Epoxidation with Nitrous Oxide as a Terminal Oxidant. Eur. J. Inorg. Chem. 2024, 27, e202300782.

 

Nicastri, K. A.; Gerstner, N. C.; Schomaker, J. M. Progress toward the Total Synthesis of Jogyamycin Using a Tandem Ichikawa/Winstein Rearrangement. Org. Lett. 2023, 25, 8279–8283.

 

Ward, R. M.; Hu, Y.; Tu, N.; Schomaker, J. M. Solvent Effects on the Chemo- and Site-Selectivity of Transition Metal-Catalyzed Heterogeneous Nitrene Transfer Reactions: Alternatives to Chlorinated Solvents. ChemSusChem 2023, 17, e202300964.

Lee, K.; Seo, K.; Dehghany, M.; Hu, Y.; Trinh, A.; Schomaker, J. M. An Overview of N-Heterocycle Syntheses Involving Nitrene Transfer Reactions. Heterocycles from Carbenes and Nitrenes: Methods, Reactions and Synthetic Applications; Doyle, M. P., Xu, X. Eds.; Topics in Heterocyclic Chemistry, Vol. 59; Springer International Publishing, 2023; pp 313–377.

Dequina, H. J.; Jones, C. L.; Schomaker, J. M. Recent Updates and Future Perspectives in Aziridine Synthesis and Reactivity. Chem 2023, 9, 1658–1701.

Trinh, T. A.; Schomaker, J. M. Unnatural α-Amino Acid Synthesis. Nat. Synth. 2023, 2, 600–601.

Chanda, B.; Ursulaez, W. C.; Schomaker, J. M.; Jones, C. L.; Dehghany, M. Compounds and Methods for Forming Ion Channels in Biological Membranes. US2023/0060873A1, 2023.

2022

Choi, I.; Trenerry, M.; Lee, K.; King, N.; Berry, J. F.; Schomaker, J. M. Divergent C-H Aminations and Iminations by Tuning Electrochemical Reaction Potentials. ChemSusChem 2022, 15, e202201662.

Fu, Y.; Zerull, E. E.; Schomaker, J. M.; Liu, P. Origins of Catalyst-Controlled Selectivity in the Ag-Catalyzed Regiodivergent C-H Amination. J. Am. Chem. Soc. 2022, 144, 2735-2746.

Liu, W.; Choi, I.; Zerull, E. E.; Schomaker, J. M. Tunable Silver-Catalyzed Nitrene Transfer: From Chemoselectivity to Enantioselective C-H Amination. ACS Catal. 2022, 12, 5527-5539.

Vine, L. E.; Schomaker, J. M. Back to Basics. Nat. Chem. 2022, 14, 1093-1094.

Zerull, E. E.; Schomaker, J. M. Chiral Amine Synthesis Refashioned. Nat. Synth. 2022, 1, 506-507.

Ward, R. M.; Schomaker, J. M. C-H to C-N Bonds via Radical-Mediated Chemistry. Handbook of CH-Functionalization; Maiti, D. Ed.; Wiley-VCH GmbH, 2022.

Zerull, E. E.; Kim, J.; Trinh, A.; Schomaker, J. M. C-H Functionalization via Asymmetric Nitrene Transfer. Handbook of CH-Functionalization; Maiti, D. Ed.; Wiley-VCH GmbH, 2022.

Carrasquel-Ursulaez, W.; Dehghany, M.; Jones, C. L.; Idikuda, V.; Lu, B.; Schomaker, J. M.; Chanda, B. Acylated and Alkylated Benzo(crown-ethers) Form Ion-Dependent Ion Channels in Biological Membranes. Biophys.J. 2022, 121, 1105-1114.

Fu, Y.; Zerull, E. E.; Schomaker, J. M.; Liu, P. Origins of Catalyst-Controlled Selectivity in Ag-Catalyzed Regiodivergent C–H Amination. J. Am. Chem. Soc. 2022, 144, 2735-2746.

Nicastri, K. A.; Zappia, S. A.; Pratt, J. C.; Duncan, J. M.; Guzei, I. A.; Fernández, I.; Schomaker, J. M. Tunable Aziridinium Ylide Reactivity: Noncovalent Interactions Enable Divergent Product Outcomes. ACS Catal. 2022, 12, 1572–1580.

Vine, L.E.; Schomaker. J. M. Pd-Catalyzed Heck-Type Reactions of Allenes for Stereoselective Syntheses of Substituted 1,3-Dienes. Eur. J. Org. Chem. 2022, 28, e202103507.

2021

Hu, Y.; Schomaker, J. M. Recent Developments and Strategies for Mutually Orthogonal Bioorthogonal Reactions. ChemBioChem 2021, 22, 3254-3262.

Dehghany, M.; Schomaker, J. M. Silver-Catalyzed Enantioselective Functionalizations of Alkenes and Alkynes: A Short Review. Curr. Opin. Green Sustain. Chem. 2021, 30, 100483.

Vine, E. L.; Reeves, R. D.; Landwehr, E. M.; Fernández, I.; Schomaker, J. M. Scope and Mechanistic Investigations of Pd-Catalyzed Coupling/Cyclization and Cycloisomerization of Allenyl Malonates. ACS Catal. 2021, 11, 9485–9494.

Ju, M.; Schomaker, J. M. Nitrene Transfer Catalysis for Enantioselective C-N Bond Formation. Nat. Rev. Chem. 2021, 5, 580-594

Ward, R. M.; Schomaker, J. M. Allene Trifunctionalization via Amidyl Radical Cyclization and TEMPO Trapping. J. Org. Chem. 2021, 86, 8891-8899.

Dequina, H. J.; Nicastri, K. A.; Schomaker. J. M. Additions of N, O, and S heteroatoms to metal-supported carbenes: Mechanism and synthetic applications in modern organic chemistry. 3rd Symposium in Carbene and Nitrene Chemistry; Pérez, P. Eds.; Advances in Organometallic Chemistry, Vol. 76; Elsevier, 2021; pp 1-100.

2020

Carrasquel Ursulaez, W.; Reeves, R. D.; Dehghany, M.; Jones, C.; Schomaker, J. M.; Chanda, B. Re-evaluation of the Mechanism of Cytotoxicity Dialkylated Lariat Ether Compounds. RSC Adv. 2020, 10, 40391-40394.

Hu, Y.; Robert, J. M.; Kilgore, H.; Mat Lani, A. S.; Raines, R. T.; Schomaker, J. M. Triple, Mutually Orthogonal Cycloadditions Through the Design of Electronically Activated SNO-OCTs. J. Am. Chem. Soc. 2020, 142, 18826–18835.

Vine, L. E.; Zerull, E. E.; Schomaker, J. M. Taming Nitrene Transfer with Silver Catalysts. Synlett, 2020, 32, 30-44.

Ju, M.; Zerull, E. E.; Roberts, J. M.; Huang, M.; Schomaker, J. M. Silver-Catalyzed Enantioselective Propargylic C–H Bond Amination through Rational Ligand Design. J. Am. Chem. Soc. 2020, 142, 12930–12936.

Lu, L.; Ward, R. M.; Schomaker, J. M. Regioselective Intramolecular Allene Amidation Enabled by an EDA Complex. Eur. J. Org. Chem. 2020, 26, 13783 –13787.

Gerstner, N. C.; Nicastri, K. A.; Schomaker, J. M. Strategies for the Synthesis of Pactamycin and Jogyamycin. Angew. Chem. Int. Ed. 2021, 60, 14252-14271.

 

Huang, M.; Paretsky, J.; Schomaker, J. M. Rigidifying Ag(I) Complexes for Selective Nitrene Transfer. ChemCatChem. 2020, 12, 3076-3081.

Nicastri, K.; Schomaker, J. M. 1, 2-Azide Migration Enables Synthesis of β-Difluoroalkyl Azides. Chem. 2020, 6, 327-329.

**Preview for Ning et. al. Synthesis of β-Difluoroalkyl Azides via Elusive 1,2-Azide Migration. Chem. 2020, 6, 486-496.**

 

Schomaker, J. M. Interview with Jennifer M. Schomaker. Org. Chem. Front., 2020, 7, 442-444.

 

Eshon, J.; Nicastri, K.; Schmid, S. C.; Raskop, W.; Guzei, I. A.; Fernández, I.; Schomaker, J. M. Intermolecular [3+3] Ring-Expansion of Aziridines to Dehydropiperidines through the Intermediacy of Aziridinium Ylides. Nat. Commun. 2020, 11, 1273.

Corbin, J. R.; Ketelboeter, D. R.; Fernández, I.; Schomaker, J. M. Biomimetic Imino-Nazarov Cyclizations via Eneallene Aziridination. J. Am. Chem. Soc. 2020, 142, 5568-5573.

Reeves, R. D.; Kinkema, C. N.; Landwehr, E. M.; Vine, L. E.; Schomaker, J. M. Stereodivergent Metal-Catalyzed Allene Cycloisomerizations. Synlett., 2020, 31, 627-631.

2019

Liu, L.; Ward, R. M.; Schomaker, J. M. Mechanistic Aspects and Synthetic Applications of Radical Additions to Allenes. Chem. Rev. 2019, 119, 12422-12490.

Ju, M.; Guan, W.; Schomaker, J. M.; Harper, K. C. Sequential Reduction of Nitroalkanes Mediated by CS₂ and Amidine/Guanidine Bases: A Controllable Nef Reaction. Org. Lett. 2019, 21, 8893-8898.

Gerstner, N. C.; Schomaker, J. M. Stereocontrolled Synthesis of the Aminocyclopentitol Core of Jogyamycin via an Ichikawa Rearrengment Reaction. J. Org. Chem. 2019, 84, 14092–14100.

Scamp, R. J.; Sheffer, B.; Schomaker, J. M. Regioselective Differentiation of Vicinal Methylene C-H Bonds Enabled by Silver-Catalyzed Nitrene Transfer. Chem. Commun. 2019, 55, 7362-7365.

Ju, M.; Huang, M.; Vine, L.; Dehghany, M.; Roberts, J. M.; Schomaker, J. M. Tunable, Catalyst-Controlled Syntheses of β- and γ-Amino Alcohol Motifs Enabled by Silver Complexes. Nat. Catal. 2019, 2, 899-908.

Dehghany, M.; Eshon, J.; Roberts, J. M.; Schomaker, J. M. Silver-Catalyzed Carbene, Nitrene, and Silylene Transfer Reactions. Silver in Organic Synthesis; Chao-Jun, L.; Xihe, B., Eds.; Wiley-VCH Verlag GmbH & Co.; Weinheim, 2019; pp 439-532.

2018

Eshon, J.; Foarta, F.; Landis, C. R.; Schomaker, J. M. α-Tetrasubstituted Aldehydes through Electronic and Strain-Controlled Branch-Selective Stereoselective Hydroformylation. J. Org. Chem. 2018, 83, 10207-10220.

Eshon, J.; Gerstner, N. C.; Schomaker, J. M. Oxidative Allene Amination for the Synthesis of Nitrogen-Containing Heterocycles. Arkivoc 2018, 6, 204-233.

Mat Lani, A. S.; Schomaker, J. M. Site-Selective, Catalyst-Controlled Alkene Aziridination. Synthesis 2018, 50, 4462-4470.

**Special issue dedicated to Professor Scott Denmark in honor of his 65th birthday**

Schmid, S. C.; Guzei, I. A.; Fernandez, I.; Schomaker, J. M. Ring Expansion Of Bicyclic Methyleneaziridines via Concerted, Near-Barrierless [2,3]-Stevens Rearrangements of Aziridinium Ylides. ACS Catal. 2018, 8, 7907-7914.

Tansukawat, N. D.; See, A. E.; Jiranuntarat, S.; Corbin, J. R.; Schomaker, J. M. Method for the Small-Scale Production of Deuterochloroform. J. Org. Chem. 2018, 83, 8739-8742.

Alderson, J. M.; Corbin, J. R.; Schomaker, J. M. Investigation of Transition Metal-Catalyzed Nitrene Transfer Reactions in Water. Bioorg. Med. Chem. 2018, 26, 5270-5273.

**Symposium-in-print for Laura Kiessling, Tetrahedron Prize for Creativity in Organic Chemistry 2017**

Liu, L.; Schomaker, J. M. Allene Aziridination as a Tool for the Synthesis of Complex Amines. Advances in Transition-Metal Mediated Heterocycle Synthesis; Fernandez, I., Solé, D., Eds.; Elsevier, 2018; pp 231-283.

2017

Huang, M.; Yang, T.; Paretsky, J. D.; Berry, J. F.; Schomaker, J. M. Inverting Steric Effects: Using ‘Attractive’ Non-Covalent Interactions To Direct Silver-Catalyzed Nitrene Transfer. J. Am. Chem. Soc. 2017, 139, 17376-17386.

Vinokur, A. I.; Yakovenko, A.; Liu, L.; Schomaker, J. M.; Guzei, I. A. An Enantiotropic Disorder-Partial Order Solid-State Transformation In A Molecular Solid Involving A Phase With Z’=12. Cryst. Growth Des. 2017, 17, 5984-5993.

Schmid, S. C.; Guzei, I. A.; Schomaker, J. M.  A Stereoselective [3+1] Ring Expansion Of The Synthesis Of Highly Substituted Methylene Azetidines. Angew. Chem. Int. Ed. 2017, 56, 12229-12233.

Burke, E. G.; Schomaker, J. M. Synthetic Applications Of Flexible SNO-OCT Strained Alkynes and Their Use in Postpolymerization Modifications. J. Org. Chem. 2017, 82, 9038-9046.

Alderson, J. M.; Corbin, J. R.; Schomaker, J. M. Tunable, Chemo- And Site-Selective Nitrene Transfer Reactions through the Rational Design of Silver(I) Catalysts. Acc. Chem. Res. 2017, 50, 2147-2158.

Ju, M.; Weatherly, C. D.; Guzei, I. A.; Schomaker, J. M. Chemo- and Enantioselective Intramolecular Silver-Catalyzed Aziridinations. Angew. Chem. Int. Ed. 2017, 56, 9944-9948.

Eshon, J.; Landis, C. R.; Schomaker, J. M. Regioselective Rh-Catalyzed Hydroformylation of 1,1,3-Trisubstituted Allenes Using BisDiazaPhos Ligand. J. Org. Chem. 2017, 82, 9270-9278.

Alderson, J. M.; Schomaker, J. M. Tandem Oxidative Derivatization of Nitrene Insertion Products for the Highly Diastereoselective Synthesis of 1,3-aminoalcohols. Chem. Eur. J. 2017, 23, 8571-8576.

Reeves, R. D.; Phelps, A. M.; Raimbach, W. A. T.; Schomaker, J. M. Diastereoselective Au-Catalyzed Allene Cycloisomerizations to Highly Substituted Cyclopentenes. Org. Lett. 2017, 19, 3394-3397.

Liu, L.; Gerstner, N. C.; Oxtoby, L. J.; Guzei, I. A.; Schomaker, J. M. Fluorinated Amine Stereotriads via Allene Amination. Org. Lett. 2017, 19, 3239-3242.

Burke, E. G.; Gold, B.; Hoang, T. T.; Raines, R. T.; Schomaker, J. M. Fine-Tuning Strain and Electronic Activation of Strain-Promoted 1,3-Dipolar Cycloadditions with Endocyclic Sulfamates in SNO-OCTs. J. Am. Chem. Soc. 2017, 139, 8029-8037.

Huang, M.; Corbin, J. R.; Dolan, N. S.; Fry, C. G.; Vinokur, A.; Guzei, I. A.; Schomaker, J. M. Synthesis, Characterization, And Variable-Temperature NMR Studies Of Silver(I) Complexes For Selective Nitrene Transfer. Inorg. Chem. 2017, 56, 6725-6733.

Weatherly, C. D.; Alderson, J. M.; Berry, J. F.; Hein, J.; Schomaker, J. M. Catalyst-Controlled Nitrene Transfer by Tuning Metal:Ligand Ratios: Insight into the Mechanisms of Chemoselectivity. Organometallics 2017, 36, 1649-1661.

Corbin, J. R.; Schomaker, J. M. Tunable Differentiation of Tertiary C-H Bonds in Intramolecular Transition Metal-Catalyzed Nitrene Transfer Reactions. Chem. Commun. 2017, 53, 4346-4349.

2016

Dolan, N. S.; Scamp, R. J.; Yang, T.; Berry, J. F.; Schomaker, J. M. Catalyst-Controlled And Tunable, Chemoselective Silver-Catalyzed Intermolecular Nitrene Transfer: Experimental And Computational Studies. J. Am. Chem. Soc. 2016, 138, 14658-14667.

Touney, E. E.; Van Hoveln, R.; Buttke, C. T.; Freidberg, M. D.; Guzei, I. A.; Schomaker, J. M. Heteroleptic Nickel Complexes for the Markovnikov-Selective Hydroboration of Styrenes. Organometallics 2016, 35, 3436–3439.

Phelps, A. M.; Chan, V. S.; Napolitano, J. G.; Krabbe, S. W.; Schomaker, J. M.; Shekhar, S. Ligand-Controlled Synthesis of Azoles via Ir-Catalyzed Reactions Of Sulfoxonium Ylides With 2-Amino Heterocycles. J. Org. Chem. 2016, 81, 4158-4169.

Gerstner, N.; Adams, C. S.; Schomaker, J. M. Stereocontrolled Syntheses of Seven-Membered Carbocycles by Tandem Allene Aziridination/[4+3] Reaction. Angew. Chem. Int. Ed. 2016, 128, 13434-13437.

Scamp, R. J.; Jirak, J. G.; Dolan, N. S.; Guzei, I. A.; Schomaker, J. M. A General Catalyst for Site-Selective C(sp³)-H Bond Amination of Activated Secondary over Tertiary Alkyl C(sp³)-H Bonds. Org. Lett. 2016, 18, 3014-3017.

Gerstner, N. C.; Adams, C. S.; Grigg, R. D.; Tretbar, M.; Rigoli, J. W.; Schomaker, J. M. Diastereoselective Synthesis of the Aminocyclitol Core of Jogyamycin via an Allene Aziridination Strategy. Org. Lett. 2016, 18, 284–287

2015

Phelps, A. M.; Alderson, J. M.; Schomaker, J. M. Metal-Catalyzed Cyclization Reactions of Allenes. Science of Synthesis; Gao, S.; Ma, S., Eds.; Thieme: Stuttgart, Germany, 2015; pp 317-347.

Burke, E. G.; Schomaker, J. M. Oxidative Allene Amination for the Synthesis of Azetidin-3-ones. Angew. Chem. Int. Ed. 2015, 54, 12097-12101.

Schmid, S. C.; Van Hoveln, R. J.; Rigoli, J. W.; Schomaker, J. M. Development of N-Heterocyclic Carbene-Copper Complexes for 1,3-Halogen Migration. Organometallics 2015, 34, 4164-4173.

Croisant, M. F.; Van Hoveln, R. J.; Schomaker, J. M. Formal Dyotropic Rearrangements In Organometallic Transformations. Eur. J. Org. Chem. 2015, 2015, 5897-5907.

Van Hoveln, R. J.; Hudson, B. M.; Wedler, H. B.; Bates, D. M.; Le Gros, G.; Tantillo, D. J.; Schomaker, J. M. Mechanistic Studies of Copper(I)-Catalyzed 1,3-Halogen Migration. J. Am. Chem. Soc. 2015, 137, 5346–5354.

2014

Alderson, J. M.; Phelps, A. M.; Scamp, R. J.; Dolan, N. S.; Schomaker, J. M. Ligand-Controlled, Tunable Silver-Catalyzed C-H Amination. J. Am. Chem. Soc. 2014, 136, 16720-16723.

Van Hoveln, R.; Schmid, S.; Schomaker, J. M. 1,3-Halogen Migration as an Entry to Aryl Coppers from an Unintuitive Starting Material. Org. Biomol. Chem. 2014, 12, 7655-7658.

Van Hoveln, R. J.; Schmid, S. C.; Tretbar, M.; Buttke, C.; Schomaker, J. M. Formal Asymmetric Hydrobromination of Styrenes via Copper-Catalyzed 1,3-Halogen Migration. Chem. Sci. 2014, 5, 4763-4767.

 Adams, C. S.; Grigg, R. D.; Schomaker, J. M. Complete Stereodivergence in the Synthesis of 2-Amino-1,3-diols from Allenes. Chem. Sci. 2014, 5, 3046-3056.

Adams, C. S.; Grigg, R. D.; Schomaker, J. M. Aminosugar Motifs via an Allene Aziridination Strategy. Tetrahedron 2014, 70, 4128-4134.

Adams, C. S.; Weatherly, C. D.; Burke, E. G.; Schomaker, J. M. The Conversion of Allenes to Strained Three-Membered Heterocycles. Chem. Soc. Rev. 2014, 43, 3136-3163.

Rigoli, J. W.; Guzei, I. A.; Schomaker, J. M. Aminodiols via Stereocontrolled Oxidation of Methyleneaziridines. Org. Lett. 2014, 16, 1696-1699.

Scamp, R. J.; Rigoli, J. W.; Schomaker, J. M. Chemoselective Silver-Catalyzed Nitrene Insertion Reactions. Pure Appl. Chem. 2014, 86, 381-393.

2013

Rigoli, J. W.; Weatherly, C. D.; Alderson, J.; Vo, B. T.; Schomaker, J. M. Tunable, Chemoselective Amination via Silver Catalysis. J. Am. Chem. Soc. 2013, 135, 17238-17241.

Weatherly, C. D.; Guzei, I. A.; Schomaker, J. M. Stereocontrolled Synthesis of 1,3-Diamino-2-ols by Aminohydroxylation of Bicyclic Methylene-Aziridines. Eur. J. Org. Chem. 2013, 2013(18), 3667-3670.

Phelps, A. M.; Dolan, N. S.; Connell, N. T.; Schomaker, J. M. Divergent Reactivity of Allene-containing α-Diazoesters using Cu and Rh Catalysts. Tetrahedron 2013, 69, 5614-5621.

Grigg, R. D.; Schomaker, J. M. Activating Group Recycling: A Fresh Approach to Arene Functionalization. Synlett 2013, 24, 401.

Rigoli, J. W.; Weatherly, C. D.; Vo, B. T.; Neale, S.; Meis, A. R.; Schomaker, J. M. Chemoselective Allene Aziridination via Ag(I) Catalysis. Org. Lett. 2013, 15, 290-293.

Schomaker, J. M.; Boralsky, L. A.; Rigoli, J. W.; Hershberger, J. C. Efficient Processes to Prepare Asymmetric, Hetereoatom-Bearing Stereotriads via Allene Oxidation. 2013-US-79511, 2013.

2012

Grigg, R. D.; Van Hoveln, R.; Schomaker, J. M. Copper-Catalyzed Recycling of Halogen Activating Groups via 1,3-Halogen Migration. J. Am. Chem. Soc. 2012, 134, 16131-16134.

 

Adams, C. S.; Boralsky, L. A.; Guzei, I. A.; Schomaker, J. M. Modular Functionalization of Allenes to Aminated Stereotriads. J. Am. Chem. Soc. 2012, 134, 10807-10810.

 

Grigg, R. D.; Rigoli, J. W.; Van Hoveln, R.; Neale, S.; Schomaker, J. M. Beyond Benzyl Grignards: Facile Generation of Benzyl Carbanions from Styrenes. Chem. Eur. J. 2012, 18, 9391-9396.

 

Weatherly, C. D.; Rigoli, J. W.; Schomaker, J. M. Synthesis of 1,3-Diaminated Stereotriads via Rearrangement of 1,4-Diazaspiro[2.2]pentanes. Org. Lett. 2012, 14, 1704–1707.

 

Rigoli, J. W.; Boralsky, L. A.; Hershberger, J. C.; Meis, A. R.; Guzei, I. A.; Schomaker, J. M. 1,4-Diazaspiro[2.2]pentanes as a Flexible Platform for the Synthesis of Diamine-Bearing Stereotriads. J. Org. Chem. 2012, 77, 2446–2455.

 

Rigoli, J. W.; Grigg, R. D.; Pearce, S. D.; Schomaker, J. M. Synthesis of Propargylic and Allenic Carbamates via the C-H Amination of Alkynes. Org. Lett. 2012, 14, 280-283.

 

Gladysz, J.; Ball, Z.; Bertrand, G.; Blum, S. A.; Dong, V. M.; Dorta, R.; Hahn, F. E.; Humphrey, M. G.; Jones, W. D.; Klosin, J.; Manners, I.; Marks, T. J.; Mayer, J. M.; Rieger, B.; Ritter, J. C.; Sattelberger, A. P.; Schomaker, J. M.; Yam, V. W. Organometallics Roundtable 2011. Organometallics 2012, 31, 1–18.

Rigoli, J. W.; Moyer, S. A.; Pearce, S. D.; Schomaker, J. M. α,β-unsaturated Imines via Ru-Catalyzed Coupling Of Allylic Alcohols And Amines. Org. Biomol. Chem. 2012, 10, 1746-1749

2011

Kulshrestha, A.; Schomaker, J. M.; Holmes, D.; Staples, R. J.; Jackson, J. E.; Borhan, B. Selectivity In The Addition Reactions of Organometallic Reagents To Aziridine-2-carboxyaldehydes: The Effects Of Protecting Groups And Substitution Patterns. Chem. Eur. J. 2011, 17, 12326-12339.

 

Grigg, R. D.; Schomaker, J. M.; Timokhin, V. C-H Amination/Cyclocarbonylation of Allene Carbamates: A Versatile Platform for the Synthesis of α,β-Unsaturated γ-Lactams. Tetrahedron 2011, 67, 4318-4326.

 

Boralsky, L. A.; Marston, D.; Grigg, R. D.; Hershberger, J. C.; Schomaker, J. M. Allene Functionalization via Bicyclic Methylene Aziridines. Org. Lett. 2011, 13, 1924-1927.

Guzei, I. A.; Gunn, E. M.; Spencer, L. C.; Schomaker, J. M.; Rigoli, J. W. Polymorphism Of 5-(pyridin-2-ylmethylene)-3-phenyl-2-methylthio-3,5-dihydro-4H-imidazole-4-one. Cryst. Eng. Comm. 2011, 13, 3444-3450.

 

2010

Boyd, W. C.; Crimmin, M.; Rosebrugh, L.; Schomaker, J. M.; Bergman, R. G.; Toste, F. D. Cobalt-Mediated, Enantioselective Synthesis Of C₂ And C₁ Dienes. J. Am. Chem. Soc. 2010, 132, 16365-16367.

Publications prior to UW-Madison:

Schomaker, J. M.; Toste, F. D.; Bergman, R. G. Cobalt-Mediated [3+2]-Annulation Reaction of Alkenes with α,β-Unsaturated Ketones, and Imines. Org. Lett. 2009, 11, 3698-3700.

Borhan, B.; Schomaker, J. M.; Bhattacharjee, S.; Korthals, K. A. Synthesis of N-Heterocycles, Beta-Amino Acids, and Allyl Amines via Aza-Payne Mediated Reaction of Ylides and Hydroxy Aziridines. U.S. Pat. Appl. Publ. 2009.

Schomaker, J. M.; Borhan, B. Total Synthesis of Haterumalides NA And NC via a Chromium-Mediated Macrocyclization. J. Am. Chem. Soc. 2008, 130, 12228-12229.

Schomaker, J. M.; Boyd, W. C.; Stewart, I. C.; Toste, F. D.; Bergman, R. G. Cobalt Dinitrosoalkane Complexes in the C-H Functionalization of Olefins. J. Am. Chem. Soc. 2008, 130, 3777-3779.

Schomaker, J. M.; Geiser, A. R.; Huang, R.; Borhan, B. Tetrasubstituted Pyrrolidines via a Tandem Aza-Payne/Hydroamination Reaction. J. Am. Chem. Soc. 2007, 129, 3794-3795.

Schomaker, J. M.; Bhattacharjee, S.; Yan, J.; Borhan, B. Diastereomerically and Enantiomerically Pure 2,3-Disubstituted Pyrrolidines from 2,3-Aziridin-1-ols using a Sulfoxonium Ylide: A One-Carbon Homologative Relay Ring Expansion. J. Am. Chem. Soc. 2007, 129, 1996-2003.

Delia, T. J.; Schomaker, J. M.; Kalinda, A. The Synthesis of Substituted Phenylpyrimidines via Suzuki Coupling Reactions. J. Heterocyclic Chem. 2006, 43, 127-131.

Zheng, T.; Narayan, R. S.; Schomaker, J. M.; Borhan, B. One-Pot Regio- and Stereoselective Cyclization of 1,2,n-triols. J. Am. Chem. Soc. 2005, 127, 6946-6947.

Schomaker, J. M.; Pulgam, V. R.; Borhan, B. Synthesis of Diastereomerically and Enantiomerically Pure 2,3-Disubstituted Tetrahydrofurans using a Sulfoxonium Ylide. J. Am. Chem. Soc. 2004, 126, 13600-13601.

Schomaker, J. M.; Borhan, B. Total Synthesis Of (+)-tanikolide via Oxidative Lactonization. Org. and Biomol. Chem. 2004, 2, 621-624.

Borhan, B.; Travis, B. R.; Schomaker, J. M. Catalytic Osmium-Assisted Oxidative Cleavage of Olefins using Peroxymonosulfuric Acid and Salts Thereof. U.S. Pat. Appl. Publ. 2003.

Schomaker, J. M.; Travis, B. R.; Borhan, B. Direct Lactonization of Alkenols Via Osmium Tetroxide-Mediated Oxidative Cleavage. Org. Lett. 2003, 5, 3089-3092.

Schomaker, J. M.; Delia, T. J. Arylation Of Halogenated Pyrimidines via a Suzuki Coupling Reaction. J. Org. Chem. 2001, 66, 7125-7128.

Siddall, T. L.; Krumel, K. L.; Emonds, M. V. M.; Schomaker, J. M.; Zettler, M. W. Process for Preparing 1-alkyl-4-(2-chloro-3-alkoxy-4-alkylsulfonylbenzoyl)-5-hydroxypyrazole and Related Compounds, 2000.

Schomaker, J. M.; Delia, T. J. 2,4,6-Trichloropyrimidine. Reaction with anilines. J. Heterocyclic Chem. 2000, 37, 1457-1462.

Delia, T. J.; Meltsner, B. R.; Schomaker, J. M. 2,4,6-Trichloropyrimidine. Reaction with sodium amide. J. Heterocyclic Chem. 1999, 36, 1259-1261.

Siddall, T. L.; Edmonds, M. V. M.; Krumel, K. L.; Schomaker, J. M. Process for Preparing 1-alkyl-4-(2-chloro-3-alkoxy-4-alkylsulfonylbenzoyl)-5-hydroxypyrazole and Related Compounds, 1998.

Schomaker, J. M. Inside the Career of a Chemical Technician. American Careers 1998, 6-7.